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Properties

 

The Properties and Benefits of the AlumiPlate™ Electrodeposited Aluminum Coating

 

 

The AlumiPlateSM aluminum plating process is a unique, patented process for electroplating high purity aluminum onto various conductive substrates.  The process produces a coating with many useful properties which can provide a very high value for customers in a wide variety of applications and industries.

 

 

 

 

  • Corrosion Resistance - The AlumiPlate aluminum coating provides excellent corrosion protection particularly in salt and/or typical industrial acidic environments.  Three mechanisms are at work in this protection.  First, the AlumiPlate layer is pore free and provides a physical barrier.  Second, pure (99.9+%) aluminum forms a thin, tenacious, non-degenerating oxide almost immediately upon contact with air.  And third, the pure aluminum layer acts as a sacrificial anode to nearly any metal that it is plated onto so that even if there are minor abrasions or scratches in the AlumiPlate layer and areas of the basis metal are exposed, the aluminum surrounding the pores will oxidize more readily, being less noble than, say, steel for example, and in this way sacrifices itself providing protection of the basis metal.  Typically a 0.5 mil AlumiPlate aluminum coating (as plated , no chromate conversion) will provide over 1,200 hours of ASTM B117 salt spray resistance (no red rust).  Chromated AlumiPlate aluminum provides an outstanding 6,000+ hrs of protection in ASTM B117 testing with no red rust!  Resistance to some acidic environments is also very high.  Kesternich testing (DIN 50018) determines a coating's resistance to SO 2 environments (typical acid rain constituent) and AlumiPlate aluminum survives an outstanding 20 cycles of the 2.0 g/l concentration and 40 cycles of the 0.2 g/l concentration testing.  Aluminum plating is an attractive alternative to cadmium for corrosion protection applications.  This makes the coating especially attractive for Marine, Off-Shore, Chemical Processing, Aerospace, Automotive and many other applications. 
    Click here for more information on Corrosion Resistance
     
  • Galvanic Corrosion Protection - The ability of the AlumiPlate aluminum coating to protect from galvanic corrosion in steel-to-aluminum (or various other dissimilar metals-to-aluminum) applications is one of the unique properties that an aluminum coating offers.  For example, in applications where steel fasteners must be used in conjunction with aluminum structures, the use of AlumiPlate aluminum-plated fasteners protects those aluminum structures from galvanic corrosion better than any other plated surface.
     
  • High Temperature (1000º F / 550º C) Applicability - Unlike many conventional plating systems which are destroyed or lost at higher temperatures, AlumiPlate aluminum offers good protection for base metals in high temperature applications.  The melting point of aluminum is 1,220ºF (660º C).   AlumiPlate aluminum will protect surfaces from corrosion at significantly higher temperatures than virtually any other conventional plated metals except for nickel.
     
  • High Purity Aluminum (99.9+%) - The fact that AlumiPlate aluminum is high purity aluminum will tell many engineers and coating specialists just about all they need to know about the surface properties of the AlumiPlate coating.  There are many applications for which the surface properties of ultra-pure aluminum make it the best solution to the problems or challenges that customers are experiencing but it cannot be used because the physical strength of the pure aluminum is insufficient for use as a component material.  The use of high purity aluminum plating combined with the physical properties of other materials such as steel, copper or even aluminum alloys allows some customers to pursue applications that they currently cannot with conventional plating systems.  Also there are some applications for which there is a need for ultra-pure aluminum as a component material. 
     
  • Non-Aqueous Process - The actual aluminum plating step in the process is done in a patented, aprotic (proton-free) , non-aqueous electrolyte which does not evolve hydrogen or expose parts to free hydrogen during plating.  While several techniques exist for the non-aqueous surface preparation of metals prior to plating, aqueous pretreatment is currently used prior to plating most metals.
    Click here for more information on Hydrogen Embrittlement
     
  • Non-Porous - This unique property of an amorphous, pore-free coating structure is one of several differences between the electrodeposited AlumiPlate layer and vapor-deposited aluminum.  A 0.3 mil (8µm) layer ensures a pore-free aluminum coating.  This property helps provide the outstanding corrosion resistance of AlumiPlate aluminum, and combined with the ability to plate the aluminum to varying thicknesses, allows the AlumiPlate layer to be bight-dipped and/or anodized (clear, colored or hard-coated) and eliminates the need for shot-peening densification after plating. 
     
  • Ductile/Formable Post-Plating - Aluminum is a soft and ductile metal.  Elongation of over 50% without fracture has been measured.  Depending on the basis metal and the intermediate layers, if any, the AlumiPlate layer can be bent, flexed, stretched, rolled or drawn without cracking or peeling.
     
  • Good Throwing Power - Because the AlumiPlate process is a true electrodeposition process done in a liquid bath, parts with complex geometries and even some with inside diameters can be plated with an even layer of aluminum.  The throwing power of AlumiPlate aluminum is similar to that of electrolytic cadmium.  Through the use of special supplemental anode racking, the AlumiPlate process can plate into some holes where the depth exceeds two diameters. 
     
  • Unrestricted Range of Thicknesses - The AlumiPlate SM process can be used to plate parts with aluminum thicknesses from 0.0001 inches to 0.015 inches (0.1 mils - 15 mils) (2 µm - 400 µm).
     
  • Uniform Thickness - The AlumiPlate process is a galvanic process and therefore follows the physical rules of any galvanic process such as electrolytic cadmium or zinc plating.  There is no pronounced "dogboning" and, with the exception of the inside of internal geometries, the aluminum layer is functionally of uniform thickness.
     
  • Non-Leveling - The AlumiPlate aluminum coating functionally conforms to the surface of the part being plated. 
     
  • Electrically Conductive - The electrical conductivity of AlumiPlate aluminum is approximately 62% that of copper and is one of the best conductors of all of the non-precious metals.  Aluminum also can offer better materials compatibility than expensive gold and silver coatings for some applications.
     
  • Thermally Conductive - Aluminum has three times the thermal conductivity of steel and can be used as a thermally conductive, corrosion resistant coating which can offer excellent matching of thermal expansion coefficients and materials compatibility.  High-purity AlumiPlate aluminum has near superconductivity at temperatures approaching Absolute Zero.
     
  • Reflectivity - Electroplated aluminum has very good specular reflectivity in the visible region (~88% @ 750µm to ~92% @ 400µm) when plated and single point diamond machined.  Reflectivity can be as high as 86% (@ 0.8µm) to 98% (@ 3.0µm).
    Click here for more information on Diamond Turnability
     
  • Scratch Resistant/Self-Healing - While high purity AlumiPlate™ aluminum is a soft metal coating (similar to cadmium plating), it is also wear-resistant in that scratches or impingements "heal" quickly (i.e., the impingement tends to "smear" or burnish the aluminum rather than to chip, crack or fracture it and even if the AlumiPlate layer is scratched through to the basis metal, the surrounding aluminum acts a a sacrificial anode to prevent oxidation corrosion of the basis metal).  Also, the oxide layer formed by anodization of the high purity AlumiPlate aluminum surface can be very hard and wear-resistant.
     
  • Excellent Surface Appearance - Aluminum offers a clean, white metal, aesthetically attractive matte surface whether as-plated or anodized.  Depending on the geometry of the parts, the surface can be precision machined, polished, bright-dipped and/or anodized, and once anodized, colored to further enhance surface appearance and/or function. 
     
  • Chemically Polishable - Aluminum can be electroplated onto a smooth surface and it can be chemically polished ("bight-dipped") for applications requiring a shiny surface appearance or reflectivity.
     
  • Anodizable on Non-Aluminum Substrates - The pore-free coating allows AlumiPlate plated parts to be clear or hard-coat anodized.  AlumiPlate aluminum can be plated onto and anodized on nearly any conductive substrate including but not limited to steels, copper, aluminum alloys, stainless alloys, beryllium and metal matrix composite materials and other various alloys.  Part geometries such as blind holes and/or intricate interior surfaces can pose challenges for anodizability applications and, because Plating With Aluminum is a rack plating process, rack marks (or contact points) must be masked during anodizing.
     
  • Electrically Non-Conductive When Anodized - The aluminum oxide layer formed by anodizing is non-conductive and can be a good electrical insulator, especially in high temperature applications.  The ability to change an electroplated surface from electrically conductive to non-conductive is unique to AlumiPlate aluminum.
     
  • Colorable During or After Anodizing - The ability to permanently color the surface of anodized aluminum makes the AlumiPlate layer an attractive choice for a wide variety of appearance or performance reasons.  The coloring could be used to color-code different types of components.  Applications abound where aesthetics play an important role such as in the Marine, Recreation, Automotive, Decorative, Sporting Goods, Die Casting, Jewelry and many other industries.
     
  • Wide Variety of Post-Treatments Available - Post-treatments applicable to the aluminum plated surface include chromate conversion coatings, clear or hard anodization, Dow conversion coatings, stripping, electroforming, electro-chemical polishing ("bright dipping"), and others.
     
  • No Heavy Metal in the Aluminization Process - While the typical current practice is to apply an intermediate strike layer of 2-5µm of nickel prior to the aluminum layer for some metals, the aluminum itself is

 

             not a heavy metal.  AlumiPlate aluminum plating can be
             a very effective replacement for cadmium or other
             heavy metal plating systems.

  • Non-Sparking - This property may allow aluminum-plated steel parts to be used in applications where steel has been disallowed for sparking reasons.
     
  • Non-Magnetic - This property makes aluminum a good coating for corrosion-prone man-made magnets such as NdFeB or "rare earth" magnets.  The non-magnetic properties of aluminum also allow its use in some interference shielding applications.
     
  • Non-Wettable by Solder - In either its as-plated form or anodized, most solder will not wet AlumiPlate aluminum.

 

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